YVO4 BeamDisplacer用結晶

Yttrium Vanadate(YVO4)は、Czochralski法で成長させた透明な結晶です。
その優れた物性から、光学偏光部品に理想的です。
広い透明度範囲と大きな複屈折を持ち、ファイバーオプティックのアイソレータやサーキュレーター、インタリーバ、ビームディスプレーサーなどの偏光光学部品において、カルサイト(CaCO3)やルチル(TiO2)結晶の優れた合成代替品となります。

Basic Properties

YVO4 TiO2 CaCO3 LiNbO3
Thermal Expansion (/℃) c-axis: 11.4 × 10-6
a-axis: 4.4 × 10-6
c-axis: 9.2 × 10-6
a-axis: 7.1 × 10-6
c-axis: 26.3 × 10-6
a-axis: 5.4 × 10-6
c-axis: 16.7 × 10-6
a-axis: 7 × 10-6
Refractive Index no: 1.9447 @ 1550 nm
ne: 2.1486 @ 1550 nm
no: 2.454 @ 1530 nm
ne: 2.710 @ 1530 nm
no: 1.6346 @ 1497 nm
ne: 1.4774 @ 1497 nm
no: 2.2151 @ 1440 nm
ne: 2.1413 @ 1440 nm
Birefringence (ne - no) 0.2039 @ 1550 nm 0.256 @ 1530 nm -0.1572 @ 1497 nm -0.0738 @ 1440 nm
Mohs Hardness 5 6.5 3 5
Deliquescence None None Weak None
Deliquescence None None Weak None
Transparency Range 0.4 - 5 µm 0.4 - 5 µm 0.35 - 2.3 µm 0.4 - 5 µm

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Basic Properties of YVO4 crystal

Transparency Range: High transmittance from 0.4 to 5 µm
Crystal Symmetry: Zircon Tetragonal, space group D4h
Crystal Cell: a = b = 7.12 A; c = 6.29 A
Density: 4.22 g/cm3
Mohs Hardness: 5, glass-like
Hygroscopic Susceptibility: Non-hygroscopic
Thermal Expansion Coefficiet: αa = 4.43 × 10-6/K; αc = 11.37 × 10-6/K
Thermal Conductivity Coefficient: //C:5.23 W/m/K; ⊥C:5.10 W/m/K
Crystal Class: Positive uniaxial with no = na = nb, ne = nc
Thermal Optical Coefficient: dna/dT = 8.5 × 10-6/K; dnc/dT = 3.0 × 10-6/K
Refractive Indices, Birefringence
(△n = ne - no)
and Walk-off Angle at 45°(ρ):
no = 1.9929, ne = 2.2154, △n = 0.2225, ρ = 6.04° at 630 nm
no = 1.9500, ne = 2.1554, △n = 0.2054, ρ = 5.72° at 1300 nm
no = 1.9447, ne = 2.1486, △n = 0.2039, ρ = 5.69° at 1550 nm
Sellmeier Equation (λ in µm): no2 = 3.77834 + 0.069736 / (λ2 - 0.04724) - 0.0108133λ2
ne2 = 4.59905 + 0.110534 / (λ2 - 0.04813) - 0.0122676λ2